|本期目录/Table of Contents|

[1]梁苏亮,吴臣仁,谌兴华,等.碳纤维负载铁酞菁催化氧化有机污染物的性能[J].现代纺织技术,2016,24(01):32-36.
 LIANG Suliang,WU Chenren,CHEN Xinghua,et al.Catalytic Oxidation of Organic Pollutants by Carbon Fiber Loaded Iron Phthalocyanine[J].Advanced Textile Technology,2016,24(01):32-36.
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碳纤维负载铁酞菁催化氧化有机污染物的性能()
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《现代纺织技术》[ISSN:1009-265X/CN:33-1249/TS]

卷:
24
期数:
2016年01期
页码:
32-36
栏目:
出版日期:
2016-01-10

文章信息/Info

Title:
Catalytic Oxidation of Organic Pollutants by Carbon Fiber Loaded Iron Phthalocyanine
文章编号:
1009-265X(2016)01-0032-05
作者:
梁苏亮吴臣仁谌兴华吕汪洋陈文兴
浙江理工大学 纺织纤维材料与加工技术国家地方联合工程实验室,杭州310018
Author(s):
LIANG Suliang WU Chenren CHEN XinghuaWangyang CHEN Wenxing
National Engineering Lab for Textile Fiber Materials & Processing Technology,Zhejiang Sci-Tech University, Hangzhou 310018,China
关键词:
铁酞菁轴向配位催化纤维碳纤维甲醛
分类号:
O643.3
文献标志码:
A
摘要:
利用4-氨基吡啶对碳纤维(CF)进行表面改性,然后通过轴向配位将铁酞菁(FePc)负载到改性碳纤维上,得到碳纤维负载铁酞菁催化材料(CF-py-FePc),并利用电感耦合等离子光谱发生仪测定铁酞菁负载量。分别以酸性红1和甲醛为底物研究其催化和电催化性能,结果表明:CF-py-FePc能有效催化活化双氧水氧化酸性红1,并能高效电催化降解甲醛,且具有良好的循环使用性能。

参考文献/References:

[1] MCKEOWN N B. Phthalocyanine Materials: Synthesis, Structure and Function[M]. Cambridge: Cambridge University Press,1998.
[2] HADASCH A, SOROKIN A, RABION A, et al. Sequential addition of H2O2, pH and solvent effects as key factors in the oxidation of 2,4,6trichlorophenol catalyzed by iron tetrasulfophthalocyanine[J]. New Journal of Chemistry,1998,22(1):45-51.
[3] SOROKIN A, SERIS J, MEUNIER B. Efficient oxidative dechlorination and aromatic ring cleavage of chlorinated phenols catalyzed by Iron sulfophthalocynine[J]. Science,1995,268:1163-1166.
[4] XIA T, MA W H, ZHANG T Y, et al. A novel approach for the oxidative degradation of organic pollutants in aqueous solutions mediated by iron tetrasulfophthalocyanine under visible light radiation [J]. Chemistrya European Journal,2002,8(6):1321-1326.
[5] CHEN X, ZOU J, LIU L, et al. Preparation of magnetic silica nanoparticlesupported iron tetracarboxyl phthalocyanine catalyst and its photocatalytic properties [J]. Applied Spectroscopy,2010,64(5):552-557.
[6] VALENTE A, PALMA C, FONSECAI M, et al. Oxidation of pinane over phthalocyanine complexes supported on activated carbon: effect of the support surface treatment [J]. Carbon,2003,41(14):2793-2803.
[7] AMIN E, NASSER S, MOHAMMAD H P. Aerobic oxidation of cyclohexane with γalumina supported metallophthalocyanines in the gas phase [J]. Applied Catalysis AGeneral, 2007,321(2):135-439.
[8] CAO R, RANJIT T, HYEJUNG K. Promotion of oxygen reduction by a bioinspired tethered iron phthalocyanine carbon nanotubebased catalyst [J]. Nature Communications,2013,4(6):2075-2076.
[9] 程丽华,黄君礼,倪福祥.Fenton试剂生成HO·的动力学研究[J].环境污染治理技术与设备,2003,4(5):12-13.
[10] SOMJATE  P, VIROTE B. Enhancement of formaldehyde degradation by amine functionalized silica/titania films [J]. Journal of Environmental Sciences,2009,21(12):1741-1746.

备注/Memo

备注/Memo:
收稿日期:2015-04-23
基金项目:国家自然科学基金重点项目(51133006)
作者简介:梁苏亮(1994-),男,湖北襄阳人,本科生,主要研究方向为负载酞菁的催化碳纤维
通信作者:吕汪洋,E-mail:luwy@zstu.edu.cn
更新日期/Last Update: 2016-03-02