|本期目录/Table of Contents|

[1]卢琴,高美萍,吕汪洋,等. 碳纳米纤维负载钴酞菁催化分解双氧水的研究[J].现代纺织技术,2012,(05):8-11.
 LU Qin,GAO Meiping,L Wangyang,et al. Research on Catalytic Decomposition of Hydrogen Peroxide Using CarbonNanofiber Supported Cobalt Phthalocyanine[J].Advanced Textile Technology,2012,(05):8-11.
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 碳纳米纤维负载钴酞菁催化分解双氧水的研究()
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《现代纺织技术》[ISSN:1009-265X/CN:33-1249/TS]

卷:
期数:
2012年05期
页码:
8-11
栏目:
出版日期:
2012-10-20

文章信息/Info

Title:
 Research on Catalytic Decomposition of Hydrogen Peroxide Using CarbonNanofiber Supported Cobalt Phthalocyanine
文章编号:
1009-265X(2012)05-0008-04
作者:
 卢琴高美萍吕汪洋陈文兴
 浙江理工大学先进纺织材料与制备技术教育部重点实验室,杭州310018
Author(s):
 LU Qin GAO Meiping L Wangyang CHEN Wenxing
 Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry ofEducation, Zhejiang SciTech University, Hangzhou 310018, China
关键词:
 双氧水催化氧化钴酞菁碳纳米纤维
分类号:
O621
文献标志码:
A
摘要:
    通过将四氨基钴酞菁(CoTAPc)以共价键方式负载到碳纳米纤维(CNF)上,制备得到了碳纳米纤维负载钴酞菁催化剂(CoTAPcCNF)。研究了CoTAPcCNF对H2O2的催化分解性能,考察了不同底物浓度、pH和温度对CoTAPcCNF催化分解H2O2的影响。结果表明:随着底物浓度的增加,CoTAPcCNF催化分解H2O2的速率加快;在碱性条件下,CoTAPcCNF具有较好的催化分解H2O2性能;温度越高,CoTAPcCNF催化分解H2O2越快,并求得该催化反应的活化能为17.917 kJ/mol。

参考文献/References:

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[2] Grootboorn N, Nyokong T. Iron perchlorophthalocyanine and tetrasulfophthalocyanine catalyzed oxidation of cyclohexane using hydrogen peroxide, chloroperoxybenzoic acid and tertbutylhydroperoxide as oxidants [J]. J. Mol. Catal. A.,2002,179:113123.〖JP〗
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[9] 鲍双玉,李艳丽,富儒年,等.碳纳米纤维负载钴酞菁催化氧化β巯基乙醇的性能研究[J].浙江理工学报,2011,28(4):490494.
[10] 〖ZK(#〗Bader H, Sturzenegger V, Hoigné J. Photometric method for the determination of low concentrations of hydrogen peroxide by the peroxidase catalyzed oxidation of N,Ndiethylpphenylenediamine (DPD)[J]. Water Research,1988,9(22):1109\|1115.

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备注/Memo

备注/Memo:
 收稿日期:2012-05-21
基金项目:国家自然科学基金项目(51133006&51103133);浙江省自然科学基金项目(Y4100094);浙江省教育厅项目(Y201019108)
作者简介:卢琴(1987-),女,广西柳州人,硕士研究生,研究方向为功能性纤维。
通讯作者:吕汪洋,Email: luwy@zstu.edu.cn
更新日期/Last Update: